This is incorrect information. Museums use plexi cases for their most valued possessions. It does not give off acidic gases per a quick look on the internet:
High-quality Plexiglas (acrylic/PMMA) does not release acidic gases; it's considered non-toxic, acid-free, and burns cleanly to produce only carbon dioxide and water, with virtually no smoke or harmful fumes, making it safe for archival use, though inferior/recycled types might off-gas, and high-heat processing (laser cutting) needs extraction